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Ce-139m shielding — lead half-value layer and dose rate

Cerium-139m

Ce-139m · Cerium, Z = 58, A = 139 · isomeric state m

Cerium-139m (Ce-139m) carries 5.22e+19 Bq/g, or 1.41e+9 Ci/g: a gigabecquerel is 19.2 pg, no weighable quantity at all. It decays by isomeric transition with a half-life of 57.58 seconds, which leaves 0% of today's activity after a day and 0% after a week.

1 GBq at 1 m reads 0.0938 mGy/h, and 1 Ci at the same distance 3.47 mGy/h, from an air kerma rate constant of 0.0938 mGy·m²/(GBq·h) — 1.2× Cs-137 and 3.3× less than Co-60, and 23 of 96 among the photon emitters carried here.

6 lines clear the 20 keV cutoff, but one of them carries 90% of the dose rate. The leading one is 754.2 keV at 98.9% of the total — its emission probability is 92.6%, which is also the highest.

This is a shield that has to be designed: 6.32 mm of lead for a factor of two and 21.2 mm for a factor of ten, or 12.6 mm of steel to halve it, at which point the mass of the shield is part of the problem. Reaching 20 µSv/h from 1 GBq at a metre takes 14.2 mm of lead.

Half-life, specific activity and dose rate

Half-life57.58 seconds (57.58 s)
Decay modeisomeric transition
Specific activity5.22e+19 Bq/g (1.41e+9 Ci/g)
Air kerma rate constant Γ (δ = 20 keV)0.0938 mGy·m²/(GBq·h)
Dose rate, 1 GBq at 1 m0.0938 mGy/h
Dose rate, 1 Ci at 1 m3.47 mGy/h
Kerma-weighted mean photon energy746.6 keV

754 keV carries 99% of the dose rate

1 further line below the 20 keV cutoff, the highest at 5.41 keV and 0.796% emission probability in all, is excluded here and from Γ. Why the two columns rank differently.

Energy (keV)Emission probability (%)Share of dose rate (%)
754.2492.698.94
34.722.857220.49
34.281.560040.28
39.751.079140.15
39.370.860560.12
40.230.218580.03

6.32 mm of lead halves this spectrum

Solved numerically across all 6 lines, narrow beam. Why not one representative energy.

MaterialHVL (mm)TVL (mm)TVL / HVL
lead6.3221.23.36
tungsten4.1213.83.36
iron12.642.23.36
copper11.237.63.36
concrete40.01343.36
water84.72843.35
aluminum36.01213.36

A single energy would give 3.32. What a spread of energies does instead.

Activity over the first hours

Ten half-lives is 9.60 minutes, so the activity moves measurably while a count is running: every figure has to carry the time it was referred to. The mean life 1/λ is 1.38 minutes.

ElapsedFraction remaining
1 half-life50.0 %
2 half-lives25.0 %
5 half-lives3.13 %
10 half-lives0.0977 %
Time to fall to 10 % of today's activity3.19 minutes
Time to fall to 1 %6.38 minutes
Time to fall to 0.1 %9.56 minutes

Limits of these dose rates

Gamma and decay calculators for Ce-139m

Other Cerium nuclides: Ce-139, Ce-141, Ce-144

Computed from the IAEA Nuclear Data Section — Livechart API (ENSDF) and the NIST X-Ray Mass Attenuation Coefficients. Derivations and citations.