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Cm-244 specific activity and alpha line energies

Curium-244

Cm-244 · Curium, Z = 96, A = 244

Curium-244 decays by alpha decay, half-life 18.11 years. Specific activity is 2.99e+12 Bq/g (80.9 Ci/g), so a gigabecquerel comes to 334 µg — weighable, but on an analytical balance. Over a year the activity falls to 96.24%, and over forty years to 21.63%.

The air kerma rate constant is small — 0.00000336 mGy·m²/(GBq·h), 2.6e+4× less than Cs-137 and 1.0e+5× less than Co-60, ranking 94 of 96 by Γ — near the bottom of the photon emitters, but above the cutoff, which 51 nuclides in this dataset are not. 1 GBq at 1 m reads 0.00000336 mGy/h, and 1 Ci at the same distance 0.000124 mGy/h. It takes 5.95 TBq at a metre to reach 20 µSv/h from the photons alone.

3 lines clear the 20 keV cutoff, but one of them carries 90% of the dose rate. The leading one is 42.8 keV at 90.1% of the total — its emission probability is 0.02635%, which is also the highest.

Shielding barely arises: 0.0558 mm of lead halves the air kerma rate and 0.207 mm takes it to a tenth, thicknesses a source capsule is likely to exceed on its own. Steel does the halving in 0.335 mm. At 1 GBq and a metre it is already under 20 µSv/h with nothing in the way. The tenth-value layer runs 3.7 times the half-value layer, not the 3.32 a single energy would give.

Alpha emission is led by 5.805 MeV at 76.9%, one of 3 recorded lines. None of it reaches through skin, so the alpha is an intake hazard rather than an external one — the photon figures above are the separate question.

Half-life, specific activity and dose rate

Half-life18.11 years (5.715e+8 s)
Decay modealpha decay
Specific activity2.99e+12 Bq/g (80.9 Ci/g)
Air kerma rate constant Γ (δ = 20 keV)0.00000336 mGy·m²/(GBq·h)
Dose rate, 1 GBq at 1 m0.00000336 mGy/h
Dose rate, 1 Ci at 1 m0.000124 mGy/h
Kerma-weighted mean photon energy51.35 keV

42.8 keV carries 90% of the dose rate

1 further line below the 20 keV cutoff, the highest at 17.60 keV and 9.04% emission probability in all, is excluded here and from Γ. Why the two columns rank differently.

Energy (keV)Emission probability (%)Share of dose rate (%)
42.820.0263590.05
152.630.001055.48
98.860.001424.46

0.0558 mm of lead halves this spectrum

Solved numerically across all 3 lines, narrow beam. Why not one representative energy.

MaterialHVL (mm)TVL (mm)TVL / HVL
lead0.05580.2073.71
tungsten0.04410.1623.68
iron0.3351.474.40
copper0.2210.9914.49
concrete7.3126.13.57
water28.495.83.38
aluminum5.6620.53.63

A single energy would give 3.32. What a spread of energies does instead.

3 alpha lines, strongest 5.805 MeV

3 recorded lines from 5.664 to 5.805 MeV, the strongest 5.805 MeV at 76.9% of 100.0% total alpha emission.

Energy (MeV)Emission probability (%)
5.804876.9
5.762623.1
5.66400.0204

Activity over decades and centuries

Ten half-lives is 181 years, which puts decay storage out of reach: 21.63% survives forty years. The mean life 1/λ, the quantity that enters an integrated dose, is 26.1 years.

ElapsedFraction remaining
1 half-life50.0 %
2 half-lives25.0 %
5 half-lives3.12 %
10 half-lives0.0977 %
Time to fall to 10 % of today's activity60.2 years
Time to fall to 1 %120 years
Time to fall to 0.1 %180 years

Limits — intake, not external dose

Gamma and decay calculators for Cm-244

Other Curium nuclides: Cm-242, Cm-243, Cm-245, Cm-246

Computed from the IAEA Nuclear Data Section — Livechart API (ENSDF) and the NIST X-Ray Mass Attenuation Coefficients. Derivations and citations.