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Na-22 shielding — lead half-value layer and dose rate

Sodium-22

Na-22 · Sodium, Z = 11, A = 22

At 2.31e+14 Bq/g — 6.25e+3 Ci/g — a gigabecquerel of Na-22 amounts to 4.33 µg, which is why activity rather than mass is how anyone states the quantity. Sodium-22 decays by electron capture with beta-plus with a half-life of 2.6018 years, falling to 76.61% of today's activity in a year and 2.4e-3% in forty years.

Among the strong external emitters here: Γ of 0.280 mGy·m²/(GBq·h) ranks 5 of 96, 3.6× Cs-137 and 1.1× less than Co-60. 1 GBq at 1 m reads 0.280 mGy/h, and 1 Ci at the same distance 10.4 mGy/h — a metre-scale hazard at gigabecquerel activities, and 71.4 MBq is already 20 µSv/h at that distance.

2 lines clear the 20 keV cutoff, but 2 of them carry 90% of the dose rate. The leading one is 1274.5 keV at 55.4% of the total — its emission probability is 99.94%, which is lower than the 179.91% of the 511.0 keV line it outranks.

This is a shield that has to be designed: 6.53 mm of lead for a factor of two and 26.6 mm for a factor of ten, or 13.5 mm of steel to halve it, at which point the mass of the shield is part of the problem. Reaching 20 µSv/h from 1 GBq at a metre takes 31.5 mm of lead.

Half-life, specific activity and dose rate

Half-life2.6018 years (8.210e+7 s)
Decay modeelectron capture with beta-plus
Specific activity2.31e+14 Bq/g (6.25e+3 Ci/g)
Air kerma rate constant Γ (δ = 20 keV)0.280 mGy·m²/(GBq·h)
Dose rate, 1 GBq at 1 m0.280 mGy/h
Dose rate, 1 Ci at 1 m10.4 mGy/h
Kerma-weighted mean photon energy933.7 keV

1275 keV leads, and 2 lines make 90%

No recorded line for Na-22 falls below the 20 keV cutoff, so this table is the whole photon spectrum. Why the two columns rank differently.

Energy (keV)Emission probability (%)Share of dose rate (%)
1274.5499.9455.36
511.00179.9144.64

6.53 mm of lead halves this spectrum

Solved numerically across all 2 lines, narrow beam. Why not one representative energy.

MaterialHVL (mm)TVL (mm)TVL / HVL
lead6.5326.64.07
tungsten4.2616.73.91
iron13.546.73.46
copper12.041.63.47
concrete43.01483.45
water90.93133.45
aluminum38.71333.45

A single energy would give 3.32. What a spread of energies does instead.

Activity over decades and centuries

Ten half-lives is 26.0 years, which puts decay storage out of reach: 2.4e-3% survives forty years. The mean life 1/λ, the quantity that enters an integrated dose, is 3.75 years.

ElapsedFraction remaining
1 half-life50.0 %
2 half-lives25.0 %
5 half-lives3.13 %
10 half-lives0.0977 %
Time to fall to 10 % of today's activity8.64 years
Time to fall to 1 %17.3 years
Time to fall to 0.1 %25.9 years

Limits of these dose rates

Gamma and decay calculators for Na-22

Other Sodium nuclides: Na-24, Na-24m

Computed from the IAEA Nuclear Data Section — Livechart API (ENSDF) and the NIST X-Ray Mass Attenuation Coefficients. Derivations and citations.