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Na-24 shielding — lead half-value layer and dose rate

Sodium-24

Na-24 · Sodium, Z = 11, A = 24

Sodium-24 (Na-24) carries 3.23e+17 Bq/g, or 8.73e+6 Ci/g: a gigabecquerel is 3.09 ng, no weighable quantity at all. It decays by beta-minus decay with a half-life of 14.956 hours, which leaves 32.88% of today's activity after a day and 0.04% after a week.

Among the strong external emitters here: Γ of 0.431 mGy·m²/(GBq·h) ranks 1 of 96, 5.6× Cs-137 and 1.4× Co-60. 1 GBq at 1 m reads 0.431 mGy/h, and 1 Ci at the same distance 15.9 mGy/h — a metre-scale hazard at gigabecquerel activities, and 46.4 MBq is already 20 µSv/h at that distance.

4 lines clear the 20 keV cutoff, but 2 of them carry 90% of the dose rate. The leading one is 2754.0 keV at 62.0% of the total — its emission probability is 99.867%, which is lower than the 99.994% of the 1368.6 keV line it outranks.

This is a shield that has to be designed: 12.9 mm of lead for a factor of two and 43.2 mm for a factor of ten, or 20.8 mm of steel to halve it, at which point the mass of the shield is part of the problem. Reaching 20 µSv/h from 1 GBq at a metre takes 57.9 mm of lead.

Half-life, specific activity and dose rate

Half-life14.956 hours (5.384e+4 s)
Decay modebeta-minus decay
Specific activity3.23e+17 Bq/g (8.73e+6 Ci/g)
Air kerma rate constant Γ (δ = 20 keV)0.431 mGy·m²/(GBq·h)
Dose rate, 1 GBq at 1 m0.431 mGy/h
Dose rate, 1 Ci at 1 m15.9 mGy/h
Kerma-weighted mean photon energy2228 keV

2754 keV leads, and 2 lines make 90%

No recorded line for Na-24 falls below the 20 keV cutoff, so this table is the whole photon spectrum. Why the two columns rank differently.

Energy (keV)Emission probability (%)Share of dose rate (%)
2754.0199.86761.95
1368.6399.99437.99
3866.150.0680.05
996.830.00210.00

12.9 mm of lead halves this spectrum

Solved numerically across all 4 lines, narrow beam. Why not one representative energy.

MaterialHVL (mm)TVL (mm)TVL / HVL
lead12.943.23.36
tungsten7.8826.53.36
iron20.870.43.38
copper18.562.53.38
concrete67.72303.41
water1444913.41
aluminum60.62063.40

A single energy would give 3.32. What a spread of energies does instead.

Activity over days and weeks

Ten half-lives is 6.23 days, so the activity moves measurably while a count is running: every figure has to carry the time it was referred to. The mean life 1/λ is 21.6 hours.

ElapsedFraction remaining
1 half-life50.0 %
2 half-lives25.0 %
5 half-lives3.13 %
10 half-lives0.0977 %
Time to fall to 10 % of today's activity2.07 days
Time to fall to 1 %4.14 days
Time to fall to 0.1 %6.21 days

Limits of these dose rates

Gamma and decay calculators for Na-24

Other Sodium nuclides: Na-22, Na-24m

Computed from the IAEA Nuclear Data Section — Livechart API (ENSDF) and the NIST X-Ray Mass Attenuation Coefficients. Derivations and citations.