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Tl-201m shielding — lead half-value layer and dose rate

Thallium-201m

Tl-201m · Thallium, Z = 81, A = 201 · isomeric state m

Thallium-201m (Tl-201m) carries 9.84e+23 Bq/g, or 2.66e+13 Ci/g: a gigabecquerel is 1.02 fg, no weighable quantity at all. It decays by isomeric transition with a half-life of 2.11 milliseconds, which leaves 0% of today's activity after a day and 0% after a week.

1 GBq at 1 m reads 0.115 mGy/h, and 1 Ci at the same distance 4.25 mGy/h, from an air kerma rate constant of 0.115 mGy·m²/(GBq·h) — 1.5× Cs-137 and 2.7× less than Co-60, and 17 of 96 among the photon emitters carried here.

7 lines clear the 20 keV cutoff, but 2 of them carry 90% of the dose rate. The leading one is 588.3 keV at 65.7% of the total — its emission probability is 94.63%, which is also the highest.

Halving the air kerma rate calls for 3.31 mm of lead, or 10.1 mm of steel where lead is unwelcome, and a factor of ten calls for 13.1 mm of lead — sheet thicknesses that a glovebox or a transport container can carry. Reaching 20 µSv/h from 1 GBq at a metre takes 9.49 mm of lead.

Half-life, specific activity and dose rate

Half-life2.11 milliseconds (0.002110 s)
Decay modeisomeric transition
Specific activity9.84e+23 Bq/g (2.66e+13 Ci/g)
Air kerma rate constant Γ (δ = 20 keV)0.115 mGy·m²/(GBq·h)
Dose rate, 1 GBq at 1 m0.115 mGy/h
Dose rate, 1 Ci at 1 m4.25 mGy/h
Kerma-weighted mean photon energy497.0 keV

588 keV leads, and 2 lines make 90%

1 further line below the 20 keV cutoff, the highest at 12.15 keV and 5.62% emission probability in all, is excluded here and from Γ. Why the two columns rank differently.

Energy (keV)Emission probability (%)Share of dose rate (%)
588.3094.6365.74
331.1086.133.02
72.876.479770.49
70.833.838610.29
83.632.858190.23
82.632.203690.17
84.870.65450.05

3.31 mm of lead halves this spectrum

Solved numerically across all 7 lines, narrow beam. Why not one representative energy.

MaterialHVL (mm)TVL (mm)TVL / HVL
lead3.3113.13.95
tungsten2.298.863.86
iron10.134.33.42
copper8.8530.33.42
concrete33.11123.38
water70.22363.37
aluminum29.71003.38

A single energy would give 3.32. What a spread of energies does instead.

Activity over the first hours

Ten half-lives is 0.0211 seconds, so the activity moves measurably while a count is running: every figure has to carry the time it was referred to. The mean life 1/λ is 0.00304 seconds.

ElapsedFraction remaining
1 half-life50.0 %
2 half-lives25.0 %
5 half-lives3.13 %
10 half-lives0.0977 %
Time to fall to 10 % of today's activity0.00701 seconds
Time to fall to 1 %0.0140 seconds
Time to fall to 0.1 %0.0210 seconds

Limits of these dose rates

Gamma and decay calculators for Tl-201m

Other Thallium nuclides: Tl-201, Tl-204

Computed from the IAEA Nuclear Data Section — Livechart API (ENSDF) and the NIST X-Ray Mass Attenuation Coefficients. Derivations and citations.